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(1S,4S)-2,5-Diphenylbicylco[2.2.2]octadiene (Hayashi ligand)

(1S,4S)-2,5-二苯基二环[2,2,2]辛-2,5-二烯

CAS: 850409-83-5

Molecular Formula: C20H18

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(1S,4S)-2,5-Diphenylbicylco[2.2.2]octadiene (Hayashi ligand) - Names and Identifiers

Name (1S,4S)-2,5-二苯基二环[2,2,2]辛-2,5-二烯
Synonyms (1S,4S)-2,5-Diphenylbicyclo[2.2.2]octadiene
(1S,4S)-2,5-Diphenylbicyclo[2,2,2]octa-2,5-diene
Bicyclo[2.2.2]octa-2,5-diene, 2,5-diphenyl-, (1S,4S)-
(1S,4S)-2,5-Diphenylbicylco[2.2.2]octadiene (Hayashi ligand)
CAS 850409-83-5

(1S,4S)-2,5-Diphenylbicylco[2.2.2]octadiene (Hayashi ligand) - Physico-chemical Properties

Molecular FormulaC20H18
Molar Mass258.36
Density1.104±0.06 g/cm3(Predicted)
Melting Point69-76°C
Boling Point383.0±42.0 °C(Predicted)
Storage Condition-20°C

(1S,4S)-2,5-Diphenylbicylco[2.2.2]octadiene (Hayashi ligand) - Risk and Safety

Risk CodesR22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin.
R43 - May cause sensitization by skin contact
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 - Wear suitable protective clothing and gloves.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
UN IDsUN 3077 9 / PGIII
WGK Germany3

(1S,4S)-2,5-Diphenylbicylco[2.2.2]octadiene (Hayashi ligand) - Introduction

(1S,4S)-2,5-diphenylbicyclo [2,2,2] oct-2, 5-diene is an organic compound. Its molecular formula is C22H18, structural formula is C6H5-C = C- C10H20-C = C- C6H5.

It is a compound with enantiomers, where (1S,4S) means that it has levorotatory configuration. It is a white solid, insoluble in water at room temperature, soluble in organic solvents such as ethanol and ether.

(1S,4S)-2,5-diphenylbicyclo [2,2,2] octa-2, 5-diene has a wide range of applications in the field of chemical research. It can be used as a chiral inducer and synthetic intermediate, and is widely used in organic synthesis reactions, such as asymmetric catalytic reactions.

(1S,4S)-2,5-diphenylbicyclo [2,2,2] octyl -2,5-diene is generally prepared by synthetic chemical methods. The specific synthetic route can be selected according to specific needs, and the common method is to synthesize by Grignard reagents and cyclopentadiene.

No clear toxicity data and hazards have been identified regarding the safety information of this compound. However, since it is an organic compound, it should be used in accordance with general laboratory safety practices and avoid contact with skin and inhalation of gases.
Last Update:2024-04-10 22:29:15
(1S,4S)-2,5-Diphenylbicylco[2.2.2]octadiene (Hayashi ligand)
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CAS: 850409-83-5
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Shanghai Macklin Biochemical Co., Ltd
Spot supply
Product Name: (1S,4S)-2,5-Diphenylbicyclo[2,2,2]octa-2,5-diene Visit Supplier Webpage Request for quotation
CAS: 850409-83-5
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328 Click to send a QQ message
WhatsApp: +86-18821248368
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